采用热分解和电化学沉积相结合的方法,在p-Cu2O纳米棒上沉积n-Cu2O,制备了n-Cu2 O/p-Cu2O纳米棒复合结构.通过X射线衍射分析(XRD)、扫描电镜分析(SEM)和Mott-Schottky(MS)测试研究了样品的结构、形貌以及导电类型,使用光电流密度测试考察了样品的光电化学性能,并根据电化学阻抗测试(EIS)进行了机理分析.结果表明:沉积n-Cu2O之后样品的载流子分离-转移能力大幅提升,因此n-Cu2 O/p-Cu2O纳米棒复合结构表现出良好的光电化学性能.
参考文献
[1] | De Jongh P E;Vanmaekelbergh D;Kelly J J .Photoelectrochemistry of Electrodeposited Cu2O[J].Journal of the Electrochemical Society,2000,147(2):486-489. |
[2] | 陈志钢,唐一文,张丽莎,张新,贾志勇,余颖.溶液温度和衬底对电化学沉积Cu2O薄膜形貌的影响[J].材料科学与工程学报,2005(04):570-573. |
[3] | 李龙凤,张茂林,孟祥东.溶剂热还原法制备纳米Cu2O及其光催化性能[J].材料科学与工程学报,2010(05):693-696. |
[4] | Paracchino A;Laporte V;Sivula K et al.Highly active oxide photocathode for photoelectrochemical water reduction[J].Nature Materials,2011,10(6):456-461. |
[5] | Hou Y;Li X Y;Zhao Q D et al.Fabrication of Cu2O/TiO2 nanotube heterojunction arrays and investigation of its photoelectrochemical behavior[J].Applied Physics Letters,2009,95(9):093108-093108-3. |
[6] | Huang Q;Kang F;Liu H et al.Highly aligned Cu2O/CuO/TiO2 core/shell nanowire arrays as photocathodes for water photoelectrolysis[J].Journal of Materials Chemistry A,2013,1(7):2418-2425. |
[7] | Wang M;Sun L;Lin Z et al.p-n Heterojunction photoelectrodes composed of Cu2O-loaded TiO2 nanotube arrays with enhanced photoelectrochemical and photoelectrocatalytic activities[J].Energy & Environmental Science,2013,6(4):1211-1220. |
[8] | McShane C M;Choi K S .Photocurrent enhancement of n-type Cu2O electrodes achieved by controlling dendritic branching growth[J].Journal of the American Chemical Society,2009,131(7):2561-2569. |
[9] | 朱俊武,王艳萍,张莉莉,杨绪杰,陆路德,汪信.乙二醇体系中纳米Cu2O的制备及其性能研究[J].材料科学与工程学报,2006(02):209-211. |
[10] | Zhang Z;Wang P .Highly stable copper oxide composite as an effective photocathode for water splitting via a facile electrochemical synthesis strategy[J].Journal of Materials Chemistry,2012,22(6):2456-2464. |
[11] | 吴惠明,涂江平,黎阳,袁永锋,赵新兵,曹高劭.竹碳的结构及电化学性能研究[J].材料科学与工程学报,2005(02):157-159. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%